Brush-painted superhydrophobic silica coating layers for self-cleaning solar panels

Abstract

Superhydrophobic coatings have potential applications in fouling resistance, self-cleaning, waterproofing, and drag reduction. In this work, using a facile brush-painting method for outdoor application, superhydrophobic silica coating layers were developed with high contact angle above 150°, high light-transmittance above 90 %, and strong weather resistance via three strategies: (i) hexadecyltrimethoxysilane-modified SiO2 (H-SiO2) particle agglomeration in colloidal coating solutions, and the formation of (ii) two-dimensional (2D) mud-crack patterns and (iii) three-dimensional (3D) micro-bumps. First, particle agglomeration was optimized in a mixed solution of water and ethanol with a relative permittivity of ε = 48.0. Second, high transmittance and full-covered hydrophobic properties were achieved from the silica coating layers with 2D mud-crack patterns. Third, maximal contact angle of 152.6° was obtained from the superhydrophobic silica coating layers consisting of heterogeneous 3D micro-bumps on the 2D mud-crack patterns. The superhydrophobic coating layers exhibited high light-transmittance of 90.2 % and near-zero sliding angle, making them suitable for use as self-cleaning solar panels. These brush-painted superhydrophobic silica layers have potential uses in industrial coating applications by providing self-cleaning capability, weather resistance, flexibility, and transparency.