Abstract

Fluorine-free mold flux is receiving increasing attention due to the environmental and health problems associated with using fluorinated flux in casting. However, the erosion problem in the submerged entry nozzle is still exists and not solved. Therefore, in this study, the electric field is used to improve the erosion resistance capability of the nozzle. The results show that a thick protective adhesion layer is formed on the surface of the slag-line material under the action of a negative electric field due to an electrochemical reaction. This protective layer further reacts with the CaO/SiO2 content of the fluorine-free slag-line material to generate an interfacial reaction layer composed mainly of Ca2SiO4 and CaZrO3. Due to the presence of Ca2SiO4 in the interfacial reaction layer, a small amount of crystalline transformation occurs during the cooling process. Thus, under the protection of the double protective layer generated by the action of the negative electric field, the slag-line material is not subject to the erosion of the fluorine-free mold flux, and the erosion rate is only 0.37%.

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