Abstract
Hydrothermally synthesized lead carbonate Pb2Br2(CO3), a bromine analogue of phosgenite mineral Pb2Cl2(CO3), space group P4/mbm, is structurally studied. A comparison of the bromine and chlorine phosgenite analogues is carried out. It is shown that the structure type of the formula analogues changes when fluorine or oxygen substitutes for their large halogens.
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