Abstract
Bromination of β-aminovinyl ketones (AVK) with geminal arrangement of the fluoroalkyl and amino groups gives N-bromo derivatives. Regioisomeric AVK with the amino groups in the β-position relative to the fluoroalkyl group undergo bromination under analogous conditions to give a mixture of the α-bromo and α,N-dibromo derivatives. α-Bromo derivatives of AVK disproportionate upon storage.
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Schedule a callMore From: Bulletin of the Russian Academy of Sciences Division of Chemical Science
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