Broken translational and rotational symmetries in LiMn1.5Ni0.5O4 spinel

Abstract

In condensed matter physics broken symmetries and emergence of quasi-particles are intimately linked to each other. Whenever a symmetry is broken, it leaves its fingerprints, and that may be observed indirectly via its influence on the other quasi-particles. Here, we report the strong signature of broken spin rotational symmetry induced due to long range-ordering of spins in Mn - sublattice of LiMn1.5Ni0.5O4 below Tc ~ 113 K reflected with the marked changes in the lattice vibrations using Raman scattering. In particular, the majority of the observed first-order phonon modes show a sharp shift in frequency in the vicinity of long range magnetic-ordering temperature. Phonons exist in a crystalline system because of broken translational symmetry, therefore any renormalization in the phonon-spectrum could be a good gauge for broken translational symmetry. Anomalous evolution of the few modes associated with stretching of Mn/NiO6 octahedra in the intermediate temperature range (~60–260 K) marked the broken translational symmetry attributed to the charge ordering. Interestingly same modes also show strong coupling with magnetic degrees of freedom, suggesting that charge-ordering and magnetic transition may be linked to each other.