Br, O‐Modified Cu(111) Interface Promotes CO2 Reduction to Multicarbon Products

Abstract

AbstractElectrochemical reduction of CO2 to multicarbon (C2+) products with added value represents a promising strategy for achieving a carbon‐neutral economy. Precise manipulation of the catalytic interface is imperative to control the catalytic selectivity, particularly toward C2+ products. In this study, a unique Cu/UIO‐Br interface is designed, wherein the Cu(111) plane is co‐modified simultaneously by Br and O from UIO‐66‐Br support. Such Cu/UIO‐Br catalytic interface demonstrates a superior Faradaic efficiency of ≈53% for C2+ products (ethanol/ethylene) and the C2+ partial current density reached 24.3 mA cm−2 in an H‐cell electrolyzer. The kinetic isotopic effect test, in situ attenuated total reflection Fourier transform infrared spectroscopy and density functional theory calculations have been conducted to elucidate the catalytic mechanism. The Br, O co‐modification on the Cu(111) interface enhanced the adsorption of CO2 species. The hydrogen‐bond effect from the doped Br atom regulated the kinetic processes of *H species in CO2RR and promoted the formation of *COH intermediate. The formed *COH facilitates the *CO–*COH coupling and promotes the C2+ selectivity finally. This comprehensive investigation not only provides an in‐depth study and understanding of the catalytic process but also offers a promising strategy for designing efficient Cu‐based catalysts with exceptional C2+ products.