Boron-doped biochar-nano loaded zero-valent iron to activate persulfate for the degradation of oxytetracycline

Abstract

Oxytetracycline has posed a serious environmental nuisance, and seeking environmental decontamination materials is the priority task to deal with antibiotic water contamination. Herein, boron-doped biochar loaded nano zero-valent iron composites (nZVI/BBC) were fabricated as activators of PDS for oxidative degradation of oxytetracycline hydrochloride (OTC), and the main removal mechanism was explored in detail. The results showed that Boron-doped biochar with borate ester structure (BC2O) and degree of defects are the main active sites for improving PDS activation properties. BBC could effectively prevent nZVI agglomeration and reduce nZVI passivation. The effects of calcination temperature of BBC, loading ratio and dosage of nZVI/BBC, PDS concentration, initial solution pH, pollutant concentration, and interfering ions on OTC removal by nZVI/BBC were also systematically investigated, and the optimal reaction conditions were screened: 10 wt% loading of nZVI in the composite, 1 g/L dosage of nZVI/BBC, 1 mM dosage of PDS and solution pH= 5. The cycling test showed that the removal rate of OTC by nZVI/BBC decreased from 95.3% to 70.2% after five cycles, indicating that there is excellent stability of this material. Among them, the catalyst of 10%nZVI/BBC displayed the optimal PDS activation performance, owing to the synergistic adsorption-double oxidation system, BBC as well as nZVI. The free radical quenching experiment and free radical trapping experiment proved that the degradation of OTC mainly followed the free radical pathway and SO4•− and •OH were the primary active species in the catalytic system. This study provides a practical reference for the treatment of actual antibiotic wastewater.