Abstract
AbstractThe shuttling of soluble lithium polysulfides (LiPSs) is one of the main bottlenecks to the practical use of Li–S batteries. It is reported that in situ synthesized ultrasmall vanadium nitride nanoparticles dispersed on porous nitrogen‐doped graphene (denoted VN@NG) as a catalytic interlayer solves this problem. The ultrasmall size of VN particles provide ample triple‐phase interfaces (the reactive interfaces among VN nanocatalyst, NG conductive substrate, and electrolyte) for accelerating LiPS conversion and Li2S deposition, which greatly reduces the accumulation of LiPSs in the electrolyte and therefore inhibits the shuttle effect. Their high catalytic activity is confirmed by a reduced activation energy of the Li2S4 conversion step based on temperature‐dependent cyclic voltammetric (CV) measurements and the reduced shuttle effect is detected by in situ Raman spectra. With the VN nanocatalyst, Li–S batteries have an outstanding cycling performance with a low capacity decay rate of 0.075% per cycle over 500 cycles at 2 C. A high capacity retention of 84.5% over 200 cycles at 0.2 C is achieved with a high sulfur loading of 7.3 mg cm−2.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.