Abstract
The coexistence of heavy metals and antibiotics in the environment always results in greater toxicity compared to the individual precursors. Therefore, efficient and economic technology for the simultaneous removal of antibiotics and heavy metals is essential. Herein, litchi leaves biochar carbonized at 550°C (L550) demonstrated high efficiency in co-removal of CTC (1838.1mmol/kg) and Cu (II) (1212.9mmol/kg) within wide range of pH (pH 4-7). Ionic strength obviously enhanced the Cu (II) removal but showed no significant effect on CTC removal. Although Al3+ and HPO42- decreased the adsorption capacities of CTC and Cu (II) on L550, the coexistence of Na+, K+, Mg2+, Cl-, NO3-, CO32- and SO42- showed a negligible effect on the simultaneous removal of CTC and Cu (II). Moreover, the adsorption capacities of CTC and Cu (II) on L550 were excellent in the river water, tap water, and lake water. In addition to electrostatic interactions, ion exchange governed Cu (II) adsorption, while surface complexation played a key role in CTC adsorption on L550. Our results demonstrated that litchi leaves biochar could be a promising adsorbent for remediating multi-contaminated environments.
Published Version
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