Abstract
The Schiff base ligand in the title complex, [Pt(C9H8BrN2S2)2], is deprotonated from its tautomeric thiol form and coordinated to PtII via the mercapto S and β–N atoms. The configuration about PtII is a perfect square-planar, with two equivalent Pt—N [2.023 (3) Å] and Pt—S [2.293 (1) Å] bonds. The phenyl ring is twisted against the coordination moiety Pt1/N1/N1′/S2′/S2 by 31.8 (2)°, due to the steric hindrance induced by ortho-substituted bulky Br atom.
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