Abstract
In the title compound, [Ru3(C29H30P2)(C19H17PS)(CO)9]·0.25CH2Cl2, the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru3 triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenylphosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, molecules are linked into [001] chains via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions also occur.
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