Abstract
The title compound, [Cu2(C14H13N2O)2(N3)2], was synthesized by the reaction of Cu(NO3)2·3H2O with the Schiff base 2-[1-(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN3 as the bridging ligand. The asymmetric unit contains one half-molecule, the other half being generated by the inversion center. Each CuII atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C—H⋯N hydrogen bonds.
Highlights
Crystal dataR factor = 0.035; wR factor = 0.062; data-to-parameter ratio = 12.5
The title compound, [Cu2(C14H13N2O)2(N3)2], was synthesized by the reaction of Cu(NO3)23H2O with the Schiff base 2-[1(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN3 as the bridging ligand
The asymmetric unit contains one half-molecule, the other half being generated by the inversion center
Summary
R factor = 0.035; wR factor = 0.062; data-to-parameter ratio = 12.5. The title compound, [Cu2(C14H13N2O)2(N3)2], was synthesized by the reaction of Cu(NO3)23H2O with the Schiff base 2-[1(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN3 as the bridging ligand. The asymmetric unit contains one half-molecule, the other half being generated by the inversion center. Each CuII atom shows a slightly distorted trigonal-pyramidal geometry formed by two. N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide
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