Abstract
In the title compound, [PdBr2(C20H17N3)2]·2CH3CN, the Pd atom, which lies on an inversion center, is four-coordinated in a square-planar geometry. The two imidazole rings are coplanar and nearly perpendicular to the plane formed by Pd, the coordinated imidazole C atom and one of the Br atoms, making a dihedral angle of 75.1 (2)°.
Highlights
In the title compound, [PdBr2(C20H17N3)2]2CH3CN, the Pd atom, which lies on an inversion center, is four-coordinated in a square-planar geometry
We report the crystal structure of the title compound, C40H34Br2N6Pd.2CH3CN, which exhibits two N-heterocyclic carbenes and two bromo ligands coordinated to a PdII center
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
R factor = 0.060; wR factor = 0.172; data-to-parameter ratio = 14.9. In the title compound, [PdBr2(C20H17N3)2]2CH3CN, the Pd atom, which lies on an inversion center, is four-coordinated in a square-planar geometry. The two imidazole rings are coplanar and nearly perpendicular to the plane formed by. The coordinated imidazole C atom and one of the Br atoms, making a dihedral angle of 75.1 (2)
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