Bis(μ-1-acetimido-4-phenylpyrazolone-N2:O)-μ-oxo-tetraoxodimolybdenum(VI) as its diacetonitrile adduct: a novel dinuclear molybdenum complex bridged by a 1-acetimido-4-phenylpyrazolone ligand

Abstract

The title compound, [Mo2O5(C11H10N3O)2]·2CH3CN, is a dinuclear molybdenum complex. It has crystallographic C2 symmetry with the central O atom located on a twofold rotation axis. The Mo atoms, octahedrally coordinated by four O and two N atoms, are bridged by a μ-O and two μ-pyrazolonyl groups. An intermolecular N—H⋯O hydrogen bond stabilizes the crystal packing.