Abstract

In the title compound, [Tb(C10H8N2O2)4(H2O)4][Mo(CN)8], both metal atoms are eight-coordinated. The TbIII atom displays a dodecahedral geometry, while the MoV ion exhibits a distorted square-anti­prismatic geometry. The Tb atoms are located on a special position of site symmetry , whereas the Mo atoms are located on a twofold rotation axis. The cations are linked by O—H⋯O hydrogen bonds.

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