Abstract
The metal atom of the title compound, [Zn(C13H8N3O2S)2]·C3H7NO·H2O, is O,N,O′-chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N—H⋯O and O—H⋯O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio.
Highlights
The metal atom of the title compound, [Zn(C13H8N3O2S)2]C3H7NOH2O, is O,N,O0 -chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry
One thienyl ring is disordered over two positions in a 1:1 ratio
Symmetry codes: (i) −x, −y, −z+1; (ii) −x+1, −y+1, −z+1
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.56 e Å3. Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.009 Å; disorder in main residue; R factor = 0.059; wR factor = 0.182; data-to-parameter ratio = 15.3. The metal atom of the title compound, [Zn(C13H8N3O2S)2]C3H7NOH2O, is O,N,O0 -chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N—. H O and O—H O interactions, generating a hydrogenbonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. Symmetry codes: (i) x; y; z þ 1; (ii) x þ 1; y þ 1; z þ 1
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