Abstract
A pair of linear cyanamide (NCNH2) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the CuII atom into a mononuclear unit, [Cu(NO3)2(C9H8N2O)2(NCNH2)2]. The coordination polyhedron of the Cu atom is an elongated octahedron distorted by Jahn–Teller effects. Intermolecular O—H⋯O, O—H⋯N, N—H⋯O and N—H⋯N hydrogen-bonding interactions link these units into a three-dimensional supramolecular architecture.
Highlights
A pair of linear cyanamide (NCNH2) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the CuII atom into a mononuclear unit
H N hydrogen-bonding interactions link these units into a three-dimensional supramolecular architecture
This work was supported by the Foundation of Northwest
Summary
Min = 0.18 e Å3 a College of Science, Northwest A&F University, Yangling, Shaanxi 712100, People’s. R factor = 0.041; wR factor = 0.105; data-to-parameter ratio = 13.5. A pair of linear cyanamide (NCNH2) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the CuII atom into a mononuclear unit,. The coordination polyhedron of the Cu atom is an elongated octahedron distorted by. Intermolecular O—H O, O—H N, N—H O and N—H N hydrogen-bonding interactions link these units into a three-dimensional supramolecular architecture
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