Abstract
The Sn atom in the title complex, bis[μ-pyruvic acid 4-hydroxybenzoylhydrazonato(2−)]bis[bis(3-chlorobenzyl)ethanoltin(IV)], [Sn2(C8H6Cl)4(C10H8N2O4)2(C2H6O)2], is six-coordinate with a distorted octahedral geometry, three O atoms and one N atom forming the equatorial plane. Through additional weak Sn—O bonding and hydrogen bonds, two molecules form a dimer, which has crystallographic \overline 1 symmetry. These discrete dimers are connected by hydrogen-bonding interactions into a three-dimensional supramolecular network.
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