Abstract
In the title ionic compound, [Pt(C17H23)(C34H33P3)](BF4)·2CH2Cl2, the PtII atom adopts a square-planar coordination geometry with the large (Z)-8-mesitylcyclooct-4-en-1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclooct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF4)− anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.
Highlights
In the title ionic compound, [Pt(C17H23)(C34H33P3)](BF4)2CH2Cl2, the PtII atom adopts a square-planar coordination geometry with the large (Z)-8-mesitylcyclooct-4-en-1-yl group occupying the fourth coordination site
H atoms treated by a mixture of independent and constrained refinement max = 0.85 e Å3
ThePt moiety and the mesityl group are attached to the cyclooct-4-ene motif at the 1- and 8-position in a syn configuration
Summary
{Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-j3P,P0 ,P0 0 }[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate a b a.
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