Bis[(2-aminophenyl)methanol-κ2N,O]bis(nitrato-κO)zinc(II)

Majid Esmhosseini

doi:10.1107/s1600536810030485

Majid Esmhosseini

Open Access

https://doi.org/10.1107/s1600536810030485

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Abstract

In the title compound, [Zn(NO3)2(C7H9NO)2], the ZnII atom, lying on a twofold rotation axis, is six-coordinated in a distorted octahedral geometry by two N atoms and two O atoms from two (2-aminophenyl)methanol ligands and two O atoms from two monodentate nitrate anions. Intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds stabilize the crystal structure.

Highlights

In the title compound, [Zn(NO3)2(C7H9NO)2], the ZnII atom, lying on a twofold rotation axis, is six-coordinated in a distorted octahedral geometry by two N atoms and two O atoms from two (2-aminophenyl)methanol ligands and two O atoms from two monodentate nitrate anions
H atoms treated by a mixture of independent and constrained refinement max = 0.67 e Å3
Symmetry codes: (ii) x, −y, z+1/2; (iii) x, y, z+1; (iv) x, −y+1, z+1/2

Summary

Majid Esmhosseini

H atoms treated by a mixture of independent and constrained refinement max = 0.67 e Å3. R factor = 0.088; wR factor = 0.154; data-to-parameter ratio = 22.3. In the title compound, [Zn(NO3)2(C7H9NO)2], the ZnII atom, lying on a twofold rotation axis, is six-coordinated in a distorted octahedral geometry by two N atoms and two O atoms from two (2-aminophenyl)methanol ligands and two O atoms from two monodentate nitrate anions. N—H O, O—H O and C—H O hydrogen bonds stabilize the crystal structure

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