Abstract
In the title compound, {[Zn(C10H8N2)(H2O)4](C8H4O4)}n, the ZnII atoms, lying on a twofold rotation axis, are bridged by 4,4′-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the ZnII atom adopts a slightly distorted octahedral coordination geometry involving four water molecules at the equatorial positions. The noncoordinated benzene-1,4-dicarboxylate anion, which is also located on a twofold rotation axis, bridges adjacent chains through O—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network.
Highlights
4,40 -bipyridine ligands, resulting in a linear chain along the b axis
The noncoordinated benzene-1,4-dicarboxylate anion, which is located on a twofold rotation axis, bridges adjacent chains through O—
Symmetry codes: (v) x+1/2, −y+1, z−1/2; (vi) x+1, y+1, z; (vii) −x+3/2, y+1, −z+3/2; (viii) x+1, y, z
Summary
ISSN 1600-5368 catena-Poly[[[tetraaquazinc(II)]-l-4,40 bipyridine-j2N:N0 ] benzene-1,4-dicarboxylate] Jing-Wei Xuc a College of Chemistry, Xiangtan University, Hunan 411105, People’s Republic of China, bNational Analytical Research Center of Electrochemistry and Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People’s Republic of China, and cState Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese
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