Abstract
In title complex, [Mn(C2N3)2(C10H8N2)2], the MnII ion is coordinated in a slightly distorted octahedral geometry by six N atoms. Four of the N atoms are from two chelating bipyridine ligands and two are from a pair of cis-coordinated dicyanamide ligands. The dihedral angle formed by the mean planes of the bipyridine rings is 85.93 (14)°. The central N atom of one of the dicyanamide ligands was refined as disordered over two sites with equal occupancies.
Highlights
In title complex, [Mn(C2N3)2(C10H8N2)2], the MnII ion is coordinated in a slightly distorted octahedral geometry by six
Four of the N atoms are from two chelating bipyridine ligands and two are from a pair of cis-coordinated dicyanamide ligands
The dihedral angle formed by the mean planes of the bipyridine rings is 85.93 (14)
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.008 Å; disorder in main residue; R factor = 0.056; wR factor = 0.178; data-to-parameter ratio = 13.0. In title complex, [Mn(C2N3)2(C10H8N2)2], the MnII ion is coordinated in a slightly distorted octahedral geometry by six. Four of the N atoms are from two chelating bipyridine ligands and two are from a pair of cis-coordinated dicyanamide ligands. The dihedral angle formed by the mean planes of the bipyridine rings is 85.93 (14). The central N atom of one of the dicyanamide ligands was refined as disordered over two sites with equal occupancies. Data collection: APEX2 (Bruker, 2004); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: PLATON (Spek, 2009); software used to prepare material for publication: SHELXTL (Sheldrick, 2008)
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