Abstract
In the title compound, [Ag2(C8H6N4OS)2](ClO4)2, each AgI center in the centrosymmetric dinuclear complex cation is coordinated by one pyridine N and a thiadiazole N atom of two inversion-related N-(1,3,4-thiadiazol-2-yl)pyridine-3-carboxamide ligands in an almost linear geometry [Ag—N = 2.187 (3) and 2.172 (3) A, and N—Ag—N = 171.8 (1)°]. Weak Ag⋯Ag and Ag–perchlorate interactions, together with π–π stacking interactions, link the complex cations along the a axis to form a ribbon.
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