Abstract
The asymmetric unit in the polymeric title compound, {[Ag(C12H10N4)]CH3SO3}n, comprises two Ag atoms, a 4-pyridinealdazine molecule in a general position, two 4-pyridinealdazine molecules each disposed about a centre of inversion, and two methanesulfonate anions. The Ag atoms are in linear geometries within N2 donor sets. The topology of the polymer is linear and the strands are connected into double chains via weak argentophilic Ag⋯Ag [3.2088 (10) Å] interactions that stack along the b axis interspersed by the methanesulfonate anions. These layers are consolidated in the crystal structure primarily via weak Ag⋯O contacts (Ag⋯O > 2.69 Å).
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More From: Acta Crystallographica Section E Structure Reports Online
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