Abstract
The title compound, [Pd2(C8H18P)2(C6H15P)2], has been obtained by the reaction of di-tert-butylphosphine–phosphanylidene–σ4-di-tert-butyl(methyl)phosphorane and bis(triethylphosphine)palladium(II) chloride with sodium naphthalide. [{Pd(μ-PtBu2)(PEt3)}2](Pd—Pd) is not a primary product. It crystallizes in space group P\overline 1 with one molecule in the unit cell. The molecule has a centre of symmetry at the mid-point of the Pd—Pd bond.
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