Abstract
In the crystal of the title compound, [Cu2Cl4(C50H32N9O8P3)2], the binuclear molecule is located across an inversion center. Each Cu2+ cation is coordinated by two pyridine N atoms from symmetry-related 4,4;6,6-bis(biphenyl-2,2′-diyldioxy)-2,2-bis{2-[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]phenoxy}cyclotriphosphazene (L) ligands, a pair of bridging Cl− anions and a terminal Cl− anion, forming a distorted CuCl3N2 square-pyramidal geometry. Weak intramolecular C—H⋯O and intermolecular C—H⋯N interactions occur in the crystal.
Highlights
College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial
In the crystal of the title compound, [Cu2Cl4(C50H32N9O8P3)2], the binuclear molecule is located across an inversion center
Each Cu2+ cation is coordinated by two pyridine N atoms from symmetry-related 4,4;6,6-bis(biphenyl-2,20 -diyldioxy)-2,2-bis{2-[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]phenoxy}cyclotriphosphazene (L) ligands, a pair of bridging Cl anions and a terminal Cl anion, forming a distorted CuCl3N2 squarepyramidal geometry
Summary
College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial. Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Jinan 250014, People’s Republic of China. R factor = 0.056; wR factor = 0.139; data-to-parameter ratio = 13.1. In the crystal of the title compound, [Cu2Cl4(C50H32N9O8P3)2], the binuclear molecule is located across an inversion center. Each Cu2+ cation is coordinated by two pyridine N atoms from symmetry-related 4,4;6,6-bis(biphenyl-2,20 -diyldioxy)-2,2-bis{2-[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]phenoxy}cyclotriphosphazene (L) ligands, a pair of bridging Cl anions and a terminal Cl anion, forming a distorted CuCl3N2 squarepyramidal geometry. Weak intramolecular C—H O and intermolecular C—H N interactions occur in the crystal
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