Abstract
The binuclear title compound, [Au2Fe(C9H10NOS)2(C17H14P)2]·CH2Cl2, which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1:1 dichloromethane solvate, which is disordered about a centre of inversion. There is a small deviation from linearity defined by the SP donor set [S1—Au—P1 angle is 175.35 (5) °] which is due to an intramolecular Au⋯O contact [3.080 (5) Å]. The primary intermolecular contacts between binuclear molecules are of the type C—H⋯π, and are arranged so as to form columns in the a-axis direction in which the disordered solvent molecules reside.
Highlights
The binuclear title compound, [Au2Fe(C9H10NOS)2(C17H14P)2]CH2Cl2, which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1:1 dichloromethane solvate, which is disordered about a centre of inversion
There is a small deviation from linearity defined by the SP donor set [S1—Au—P1 angle is 175.35 (5) ] which is due to an intramolecular Au O contact [3.080 (5) Å]
The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
[l-1,10 -Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-jS]gold(I)} dichloromethane solvate a b.
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