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Abstract
In the centrosymmetric dinuclear title complex, [Mn2(C16H10NO2)4(C12H8N2)2(H2O)2]·2H2O, the MnII cation is in a distorted octahedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenylquinoline-4-carboxylate anions. A pair of 2-phenylquinoline-4-carboxylate anions bridge two Mn cations, forming the dinuclear molecule. An intramoleculr O—H⋯O hydrogen bond occurs. Intermolecular O—H⋯O and O—H⋯N hydrogen bonds are present in the crystal structure.
Highlights
[Mn2(C16H10NO2)4(C12H8N2)2(H2O)2]2H2O, the MnII cation is in a distorted octahedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O
Intermolecular O—H O and O—H N hydrogen bonds are present in the crystal structure
Symmetry codes: (ii) −x, y+1/2, −z+3/2; (iii) x, −y+1/2, z−1/2; (iv) −x+1, y+1/2, −z+3/2
Summary
Bis(l-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo R factor = 0.039; wR factor = 0.113; data-to-parameter ratio = 16.2.
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