Biopolymer-Based Films Reinforced with Green Synthesized Zinc Oxide Nanoparticles.

Abstract

Nowadays, biopolymer-based films are being developed as an alternative to conventional plastic-based films, mainly because they are non-toxic, flexible, inexpensive, and widely available. However, they are restricted in their applications due to several deficiencies in their properties. Accordingly, the reinforcement of these materials with nanoparticles/nanofillers could overcome some of their shortcomings, especially those processed by green methods. Green synthesized zinc oxide nanoparticles (ZnO-NPs) are highly suggested to overcome these deficiencies. Therefore, the main aim of this work was to develop different biopolymer-based films from cellulose acetate (CA), chitosan (CH), and gelatin (GE) reinforced with ZnO-NPs prepared by casting, and to assess their different properties. The results show the improvements produced by the incorporation of ZnO-NPs (1% w/w) into the CA, CH, and GE systems. Thus, the water contact angles (WCAs) increased by about 12, 13, and 14%, while the water vapor permeability (WVP) decreased by about 14, 6, and 29%, the water solubility (WS) decreased by about 23, 6, and 5%, and the transparency (T) increased by about 19, 31, and 20% in the CA, CH, and GE systems, respectively. Furthermore, the mechanical properties were enhanced by increasing the ultimate tensile strength (UTS) (by about 39, 13, and 26%, respectively) and Young's modulus (E) (by about 70, 34, and 63%, respectively), thereby decreasing the elongation at the break (εmax) (by about 56, 23, and 49%, respectively) and the toughness (by about 50, 4, and 30%, respectively). Lastly, the antioxidant properties were enhanced by 34, 49, and 39%, respectively.