Abstract
The biomimetic oxidation of metribuzin, a pre- and post-emergence herbicide with hydrogen peroxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides [TAPFe(III)Cl], has been studied yielding 6- t-butyl-3-methylthio-1,2,4-triazine-5(4 H)-one, 4-amino-6- t-butyl-3,5(2 H,4 H)-dione and 6- t-butyl-1,2,4-triazin-3,5(2 H,4 H)-dione under various reaction conditions.
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