Abstract

Biomass is among the most promising renewable resources to provide a sustainable solution to meet the world’s increasing usage of it in biochemical and thermochemical conversion technologies. Thermochemical conversion processes (pyrolysis, gasification, and combustion) thermally convert biomass into energy-dense intermediates that can be, in turn, converted to power, liquid fuels, and chemicals. The performance of the processes and quality of the intermediates are strongly affected by endogenic and technogenic inorganics. This review highlights investigations on the effect and the fate of inorganics during pyrolysis, gasification, and combustion of lignocellulosic biomass and critically and comprehensively presents pre-treatment and post-treatment approaches for inorganic removal. During pyrolysis process, the inorganic contents can have significant catalytic effects and change the thermal degradation rate, chemical pathway, and bio-oil yield. During combustion process, the inorganic contents can bring va...

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