Biomass-derived mesopore-dominant porous carbons with large specific surface area and high defect density as high performance electrode materials for Li-ion batteries and supercapacitors

Abstract

Listen

Translate article

Porous carbons with high specific surface area and high defect density have been prepared through direct carbonization of cattle bones without any additional activators and templates. Benefiting from self-activation induced by hydroxyapatites within the cattle bones, the high-defect porous carbons obtained at 1100°C (PC-1100) possess the high specific surface area (2096m2g−1), largest mesopore volume (1.829cm3g−1), a narrow mesopore size distribution centered at approximately 4.0nm and good electrical conductivity (5141Sm−1). Due to the synergistic effect of the defects and pores, PC-1100 as the anode for Li-ion battery exhibits a high reversible capacity of 1488mAhg−1 after 250 cycles at 1Ag−1 and 661mAhg−1 after 1500 cycles at 10Ag−1. Even at 30Ag−1, PC-1100 can still deliver a high reversible capacity of 281mAhg−1, showing superior lithium storage capability. Moreover, the symmetric supercapacitor based on the PC-1100 in neat EMIM-BF4 electrolyte delivers a high energy density of 109.9Whkg−1 at a power density of 4.4kWkg−1, and maintains an energy density of 65.0Whkg−1 even at an ultrahigh power density of 81.5kWkg−1, as well as a superior cycling performance (96.4% of the capacitance retention after 5000 cycles).