Abstract
We present a simple technique to fabricate rubber-toughened biopolymer/organoclay nanocomposite coatings with highly water repellent surface wetting characteristics and strong adhesion to metal surfaces. The technique combines the principles of phase inversion and atomization of multicomponent polymer/organoclay suspensions containing a biolubricant as the nonsolvent. The biolubricant was a blend of cyclomethicone/dimethiconol oil with fruit kernel oils. The ternary system of cellulose nitrate/solvent/biolubricant was blended with rubber dispersed organoclay nanofluids. Natural, synthetic, and fluoroacrylic latex rubbers were used for the purpose. Self-cleaning superhydrophobic coatings were obtained from synthetic and fluoroacrylic rubbers whereas natural rubber containing formulations resulted in sticky superhydrophobic coatings.
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