Biodegradable aliphatic polyesters. Part II. Synthesis and characterization of chain extended poly(butylene succinate- co-butylene adipate)

Abstract

Poly(butylene succinate- co-butylene adipate) was obtained from 1,4-butanediol and dimethyl esters of succinic and adipic acids through a two step process of transesterification and polycondensation. High molecular weight polyesters were synthesized using hexamethylene diisocyanate as chain extender. The effect of chain extension reaction time and chain extender content on polyester molecular weight, thermal and mechanical properties, was investigated. Polyesters were characterized by means of nuclear magnetic resonance (NMR) spectroscopy, gel permeation chromatography (GPC), viscosity measurements, differential scanning calorimetry (DSC), X-ray diffraction (XRD) and mechanical property measurements. Chain extension reaction had as a result the significant increase of polyester molecular weight leading to increased tensile strength. Polyester crystallinity, as calculated from XRD and DSC analysis, and melting temperature decreased upon chain extension, while glass transition temperature increased. Polyester biodegradation was investigated by soil burial and enzymatic hydrolysis using the enzyme Pseudomonas fluorescens cholesterol esterase. It appears that biodegradation was affected by polyester crystallinity, rather than by its molecular weight.