Abstract

The present study examines the effect of both the pressure and peak temperature on the potential stability of the biochar produced from the slow pyrolysis of two-phase olive mill waste. On the basis of the available studies in the literature, the following properties were taken as rough indicators of the potential stability of biochars in soils: the fixed-carbon yield, the fraction of aromatic C, and the molar H:C and O:C ratios. Pyrolysis experiments were performed in a laboratory-scale fixed-bed device and planned following a central composite design. The product gas yield and composition values at the outlet of the secondary cracking reactor (a fixed-bed of activated alumina particles at 700 °C) were also analyzed as a function of pressure and peak temperature. The results from the statistical analyses indicate that both the analyzed factors have a strong influence on the distribution of the pyrolysis products, as well as on the properties of the produced biochar. The most potentially stable biochars w...

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