Abstract
The reaction of catalytic liquid-phase oxidation of olefins by molecular oxygen belongs to the most promising processes of organic synthesis and is a subject of numerous publications (see [1–3] for example). We have shown recently [4] that mononuclear rhodium organometallic complexes are active catalysts of the 1-octene oxidation by molecular oxygen. In this communication we present preliminary results of studying catalytic properties of complexes containing several metal centers, namely binuclear complexes of rhodium (+1), rhodium (+3), iridium (+1), palladium (+2), and triad complexes containing the ruthenium (+2) complex trans-[Ru(py)4(CN)2] as a central unit and rhodium (+1) or palladium (+2) complexes as terminal fragments.
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