Abstract

The novel binuclear hydroxo-bridged complexes trans-[R(PPh 3)Pd(μ-OH) 2Pd(PPh 3)R] and cis-[R(PPh 3)Pd(μ-OH)(μ-pz)Pd(PPh 3)R] (R = C 6F 5 or C 6Cl 5; pz = pyrazolate) have been prepared, and their structures assigned on the basis of NMR data.

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