Abstract
Six binary systems were studied using DTA with supplementary XRD. In Li2SO4−MSO4 systems (M=Mg, Co, Ni), a primary solid solution with α-Li2SO4 structure (high-temperature form) and an incongruent melting compound Li2My(SO4)1+y exist:y=2 with Mg andy=1 with Co and Ni. In Li2SO4−Li3XO4 systems (X=P, V), which are very different from one another, only primary solid solutions exist. In the Li2SO4−Li2B4O7 system there is neither a solid solution nor an intermediate compound. Comparisons with previous investigations are made.
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