Binary and Ternary Complexes Involved in the Systems Methioninehydroxamic Acid - Glycylglycine - Ni(II) or Cu(II) Ions

Abstract

The formation constants of binary and ternary complexes involved in the systems methioninehydroxamic acid (MX), glycylglycine (GG) and Cu(II) or Ni(II) were determined by pH-metric titration in aqueous solution at an ionic strength (I)= 0.15 M NaCl) and T = 25°C. Ternary species of the type (MX : GG : Ni(II) or Cu(II) : H) = (1 : 1 : 1 : r), (2 : 1 : 1 : r) and (1 : 2 : 1 : r) exist in the pH range ∼3 to ∼10. Differential pulse polarography (DPP) was used to follow complex formation and to study the reduction properties of these metal ions in the presence of MX, and GG. The metal oxidation states were more stabilized in the ternary systems than in the binary systems except for a few Ni(II) systems. Spectral studies in the UV-Vis-nIR were used to monitor the presence of ternary species in the Ni(II) and Cu(II) systems. In addition, EPR studies were also used to record the magnetic properties of the binary and ternary species in the Cu(II) systems.