Abstract
The dependence on concentration of the molar conductivity of aluminum chloride solutions in nitrobenzene (up to high dilutions) has been measured. The values of the molar conductivity in the concentration range 10−5–10−2 M/1 may be quantitatively interpreted in terms of concepts and laws of classical electrochemistry, assuming formation of the so-called triple ions arising from association of the primarily formed simple ions Cl− and AlCl2+ with the non-dissociated AlCl3 molecules. With increasing concentration an additional increase in association of triple and single ions occurs to form a dimeric aluminum chloride. The dissociation constants for various ionic equilibria have been established.
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