Abstract
The CuII atom in the title complex, (2,2′-bipyridine-N,N')(nitrato-O)(1-phenyl-1,3-butanedionato-O,O')copper(II), [Cu(C10H9O2)(NO3)(C10H8N2)], has a square-pyramidal coordination. Both the benzoylacetone anion and the 2,2′-bipyridine ligand chelate to the CuII atom in the equatorial plane, while a nitrate anion occupies the apical site, with a longer Cu—O distance of 2.335 (4) A. Within the delocalized enol ring of benzoylacetone, the C—C bond closest to the phenyl ring is longer than the C—C bond farthest from the phenyl ring.
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More From: Acta Crystallographica Section C Crystal Structure Communications
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