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Abstract
In the title complex, [Sn(C6H5)3(C7H3ClNO4)(CH4O)], the five-coordinate SnIV atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxylate group, three phenyl rings and a methanol molecule. The axial sites are occupied by the O atoms of the methanol molecule and the carboxylate group, while the equatorial plane is formed by the C atoms of three phenyl rings. The benzene ring of the 2-chloro-4-nitrobenzoate ligand makes dihedral angles of 66.18 (7), 74.71 (7) and 77.39 (7)° with respect to the three phenyl rings. In the crystal, the molecules are linked via intermolecular O—H⋯O and C—H⋯O hydrogen bonds into a column along the b axis.
Highlights
In the title complex, [Sn(C6H5)3(C7H3ClNO4)(CH4O)], the five-coordinate SnIV atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxylate group, three phenyl rings and a methanol molecule
The axial sites are occupied by the O atoms of the methanol molecule and the carboxylate group, while the equatorial plane is formed by the
The molecules are linked via intermolecular O—H O and C—H O hydrogen bonds into a column along the b axis
Summary
Refinement a Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul. 31900 Kampar, Perak, Malaysia, and bX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia. H atoms treated by a mixture of independent and constrained refinement max = 2.82 e Å3. In the title complex, [Sn(C6H5)3(C7H3ClNO4)(CH4O)], the five-coordinate SnIV atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxylate group, three phenyl rings and a methanol molecule. The axial sites are occupied by the O atoms of the methanol molecule and the carboxylate group, while the equatorial plane is formed by the. The benzene ring of the 2chloro-4-nitrobenzoate ligand makes dihedral angles of. 66.18 (7), 74.71 (7) and 77.39 (7) with respect to the three phenyl rings. The molecules are linked via intermolecular O—H O and C—H O hydrogen bonds into a column along the b axis
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