Beneficiation of nickeliferous laterite by reduction roasting in the presence of sodium sulfate

Abstract

In this paper, the reduction roasting of laterite ore in the absence or presence of sodium sulfate was carried out for nickel beneficiation by wet magnetic separation. Sodium sulfate is found to be capable of enhancing the reduction of laterite ore through liberating iron and nickel from Ni/Fe substituted-lizardite, as well as increasing the size of ferronickel particles considerably. When the laterite pellets were reduced at 1100°C for 60min, the average particle size of ferronickel grains was approximately 50μm in the presence of sodium sulfate, which far exceeded the size of 5–10μm in the absence of sodium sulfate. Compared with those reduced without sodium sulfate, the Ni grade of ferronickel concentrate increased from 2.33% to 9.48%, and the magnetic separation recovery of Ni increased from 56.97% to 83.01% with the addition of 20wt.% sodium sulfate. Experimental evidence showed that troilite (FeS) serves as an activating agent to accelerate melt phase formation via a low melting point (985°C) Fe–FeS eutectic. This markedly facilitated the aggregation of ferronickel particles during reduction, along with the selective enrichment of Ni by suppressing the complete metallization of Fe.