Abstract
The interaction of ozone with Prussian Blue has been studied by Mossbauer, infrared and XRD techniques. All spectral results reveal a reversible conversion of ferrocyanide to ferricyanide with preservation of the crystal skeleton. Ferric ferricyanide obtained by ozonization of ferric ferrocyanide has Mossbauer parameters different to those of an ordered Prussian Brown, which has been attributed to secondary reaction products located at the zeolite voids of the former compound.
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