Abstract
The behavior of Np(VI) in HNO3 solutions containing potassium phosphotungstate K10P2W17O61 (KPW) at various concentrations of HNO3 (1–3 M) and KPW [(1–3) × 10−3 M] was studied by spectrophotometry. The rate law and the Np(VI) transformation scheme were determined, and the effective rate constants of the Np(VI) reduction and Np(V) reproportionation were calculated.
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