Batch and fixed-bed assessment of sulphate removal by the weak base ion exchange resin Amberlyst A21

Abstract

This paper investigated sulphate removal from aqueous solutions by Amberlyst A21, a polystyrene weak base ion exchange resin. Both the pH and initial sulphate concentration were observed to strongly affect sorption yields, which were largest in acidic environments. Working under optimum operational conditions, sulphate sorption by Amberlyst A21 was relatively fast and reached equilibrium after 45min of contact between the solid and liquid phases. Sorption kinetics could be described by either the pseudo-first order (k1=3.05×10−5s−1) or pseudo-second order model (k2=1.67×10−4s−1), and both the Freundlich and Langmuir models successfully fitted the equilibrium data. Sulphate uptake by Amberlyst A21 was a physisorption process (ΔH=−25.06kJmol−1) that occurred with entropy reduction (ΔS=−0.042kJmol−1K−1). Elution experiments showed that sulphate is easily desorbed (∼100%) from the resin by sodium hydroxide solutions at pH 10 or pH 12. Fixed-bed experiments assessed the effects of the initial sulphate concentration, bed height and flow rate on the breakthrough curves and the efficiency of the Amberlyst A21 in the treatment of a real effluent. In all studied conditions, the maximum sulphate loading resin varied between 8 and 40mg(SO42−)mL(resin)−1.