Abstract

Special relativity is a fascinating and challenging branch of physics. It describes the physics of the high velocity/high energy regime, frequently turning up phenomena that appear paradoxical in view of our everyday experience. In this book we will be quite selective in our presentation of the theory of special relativity: we will concentrate on those features that we consider necessary for the later applications to relativistic quantum chemistry. We do this in good conscience, knowing that there is a vast literature on the subject, catering to a wide range of audiences—from the quite elementary to the very sophisticated. A few examples are listed in the reference list, but a visit to any nearby physics library will provide an ample selection of reading material for those wishing to delve deeper into the matter. In the present chapter we adopt a minimalist approach. We develop some of the basic concepts and formulas of special relativity, building on a rather elementary level of basic physics. The aim is to provide a sufficient foundation for those who want to proceed as quickly as possible to the more quantum chemical parts of the text. In later chapters we will introduce more advanced tools of physics and revisit some of the subjects treated here. The theory of special relativity deals with the description of physical phenomena in frames that move at constant velocity relative to each other. The classroom is one such frame, the car passing at constant speed outside the classroom is another. The trajectory of a ball being thrown up vertically in the car will look quite different whether we describe it relative to the interior of the car or relative to the interior of the classroom. In particular we will be concerned with inertial frames. We define an inertial frame as a frame where spatial relations are Euclidean and where there is a universal time such that free particles move with constant velocities. In classical Newtonian mechanics, relations between the spatial parameters and time in two inertial frames S and S’ are expressed in terms of the Galilean transformations.

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