Abstract
Relative rate experiments performed in a photochemical reactor at 293 ± 0.5 K and a total air pressure of 980 mbar were used to determine k(CH3C(O)OCH3 + Cl) = (1.93 ± 0.27) × 10−12 cm3 molecule−1 s−1 and k(CH3C(O)OCH3 + OH) = (3.18 ± 0.13) × 10−13 cm3 molecule−1 s−1. The product branching ratio for the Cl-initiated oxidation of CH3C(O)OCH3 was investigated at 293 ± 0.5 K and 980 mbar N2, air, or O2, in the presence and absence of NO. Products observed were CH3C(O)OCHO, CH3C(O)OH, HC(O)OH, CO, and CO2. The product branching ratios were dependent on NO, but not on the oxygen partial pressure.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
