Abstract
A binap-ligated copper iodide dimer embedded on a metal−organic framework (MOF) was designed as an effective photoredox catalyst by Dan Li, Jian He, and co-workers in their Research Article (e202300233). Under visible-light irradiation, this heterogenized copper(I) complex promotes multiple iminyl radical-mediated reactions initiated by N−O bond cleavage, with significantly enhanced photocatalytic activity compared to its homogeneous counterparts. The use of a hydroxamic acid linker for post-synthetic modification renders the catalyst recyclable.
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