Abstract
We report on an investigation on autoionization of Rydberg electrons of the nitric oxide molecule in strong, static electric fields. The excitation was done via various rotational states of the A 2Σ+ intermediate state (v′=0) and with polarization parallel or perpendicular to the electric field. The splitting of the autoionizing Rydberg states into overlapping Stark manifolds is resolved for excitation above the saddlepoint created by the field. We observe that the competing decay between photoionization and predissociation can lead to an incorrect interpretation of threshold energy. The photoionization spectrum of NO Rydberg series attached to various rotational thresholds is very similar owing to weak rotational coupling. The experimental results are accurately simulated by quantum calculations based on multichannel quantum defect theory (MQDT). A more intuitive formulation of the average behavior of the photoionization cross section is developed that accounts for the suppression of ionization near the threshold due to competing predissociating channels.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
